My understanding is that PCA is exploratory FA, so it will look for latent factors - which will be the ones produced in your rotated matrix at the end.
What SPSS doesn't do is confirmatory FA, this is used once you have your factors and want to confirm they still apply/apply to a different sample. You can do this using Mplus, AMOS or Lisreal, but not SPSS.
(I think anyway!)