Actually there are many PhD projects which dnt require app forms, just mail yr CV. Its best 1st to contact the tutor of the project, by 1st enquiring about the project, then reply acknowledging yr interest in the area stating yr situation and yr competence. This would also be further aided with good references from your tutors, which hopefully would support u.Usually the interview is the tough part, but is the place to prove yourself. good luck!
P.S. if your work experience was subject related, you would have a massive advantage