Hi ShahSeville,
I hope I have correctly understood what you are asking!
In most cases, I would *not* recommend using means and SDs to describe raw data from Likert scales. This is because the data is not continuous (it is either interval or ordinal, depending on how you interpret it). More appropriate descriptive statistics could be the median or modal ratings across the five questions to report an average rating and the range, interquartile range etc. to report the dispersion of ratings.
But if you did want to get the SD ... Maybe when you are running the descriptive statistics, you are getting SDs by item because of the way your data is set out in SPSS. Are the ratings from your five questions set out in five separate columns? If that is the case and you want to get an SD of ratings from all five questions collapsed, then you need to put the ratings into a single column. You can do this by restructuring your data by clicking on "Data" and then "Restructure...". Then you need to select "Restructure selected variables into cases" and select "One" for "How many variable groups do you want to restructure". Next move the five questions in the box "Target Variable" and keep any other variables you want by moving them to the "Fixed Variables" box.
Hope that helps!