I would say it is too long.
If a PhD is 6 main chapters plus introduction and conclusion, then each main chapter should be around 10.000 words (did a science PhD, maybe it is different in other disciplines). I broke my methodology into two chapters of 10K.
I have the same kind of problem but from the opposite direction - my supervisor is suggesting something needs a chapter of its own, but it's going to be a silly little chapter compared to the others and I'm reluctant to do that. I have a sense, as Dr Jeckyll has described, that chapters should be roughly balanced, especially since I got criticised for that very issue at Masters level!
I think it's quite common to have long qualitative chapters. Have a think, though, about whether it might be broken down into a couple of main themes, or segments of your argument, that could form separate chapters. This might make it more readable and easier for the examiners to digest.
My main qualitative chapter was between 20000 and 25000 words. I was convinced I would be told at the viva that I have too shorten it, but they didn't say anything, just commented on how thorough the analysis was. (Trying to squeeze it into a paper is rather hard though...)
So I would say it probably depends on your examiners!
Good luck. :)
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